61967-12-2

Usage

Physical Appearance

Pale yellow, oily liquid

Natural Sources

Found in the bark of cinnamon trees and in the leaves of Perilla frutescens

Uses

Commonly used in the fragrance and flavor industry
Imparts a sweet, balsamic scent reminiscent of cinnamon
Used in the production of perfumes, soaps, and other cosmetic products
Potential applications in pharmaceuticals
Used as a chemical intermediate for the synthesis of other compounds

Upstream product

• 119-61-9 benzophenone 
• 4784-77-4 (E/Z)-crotyl bromide 
• 21969-32-4 (1-methylallyl)magnesium chloride 
• 1106964-40-2 1-methylprop-2-ene-1-sulfonyl chloride 
• 37506-25-5 trimethyl(1-methyl-2-propenyl)stannane 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 53317-08-1 9-allyl-9-bora-bicyclo[3.3.1]nonane 

Downstream Products

• 42842-58-0 1,2-dimethyl-3-phenyl-1H-indene 
• 34663-33-7 (2-methylbuta-1,3-diene-1,1-diyl)dibenzene 
• 1617496-10-2 methyl 2-(2-methyl-3-phenyl-1H-inden-1-yl)acetate 
• 25201-44-9 2-methyl-1-phenyl-3-butene-1-ol 
• 304459-85-6 4-methyl-1-phenyl-hex-5-en-3-ol 
• 119-61-9 benzophenone 
• 85924-62-5 1,1-diphenylpent-3-enol 

Relevant academic research and scientific papers

[bmim][Br] as an Inexpensive and Efficient Medium for the Barbier-Type Allylation Reaction Using a Catalytic Amount of Indium: Mechanistic Studies

Barbier-type allylation reactions of aldehydes and ketones have been carried out with both unsubstituted and γ-substituted allyl bromides using only a catalytic amount (0.1 equiv.) of In metal in [bmim][Br], but not in H2O, organic solvents, or

Synthesis of highly substituted indene derivatives by Br?nsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols

An efficient synthetic method to prepare highly substituted indenes in moderate to excellent yields that relies on Br?nsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols under mild conditions is described.

The catalyzed desulfinylative allylation of carbonyl compounds with alk-2-enesulfonyl chlorides and silyl alk-2-enesulfinates

Coupling up with sulfonyl chlorides: An ene reaction of alkenes with SO2·BCl3 permits the one-pot conversion of simple alkenes into b,g-unsaturated sulfonyl chlorides or sulfinic silyl esters. These compounds can then be used as nucleophilic allylating agents with aldehydes and ketones to generate the corresponding homoallylic alcohols (see scheme) with good chemo-and diastereoselectivity in the presence of a suitable catalyst and reducing agent.

Electrogenerated Zinc as the Catalyst in the Allylation of Carbonyl Compounds. Direct Synthesis of α-Methylene-γ-Lactones

The electroreduction of a catalytic amount of ZnBr2 in acetonitrile provided a active Zn*, able to catalyze the reductive coupling of allyl bromides and chlorides with carbonyl compounds with high regioselectivity.Substituted α-methylene γ-lactones were o

Photoinduced Allylation of Aromatic Carbonyl Compounds by Allylic Stannanes

irradiation of aromatic carbonyl compounds and allyl-, 2-methyl-2-propenyl, or 3-methyl-2-butenyltrimethylstannanes in acetonitrile afforded δ,γ-unsaturated alcohols as major product.A photoinduced electron transfer mechanism is proposed for the allylations.