428818-80-8Relevant academic research and scientific papers
An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides
Tang, Wenjun,Chi, Yongxiang,Zhang, Xumu
, p. 1695 - 1698 (2002)
Matrix presented An ortho-substituted BIPHEP ligand, o-Ph-hexaMeO-BIPHEP (1), is designed and synthesized. Compared with chiral biaryl phosphines without ortho substituents such as BINAP and MeO-BIPHEP, o-Ph-hexaMeO-BIPHEP shows higher enantioselectivitie
Ortho substituted chiral phosphines and phosphinites and their use in asymmetric catalytic reactions
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, (2008/06/13)
3,3′-Substituted chiral biaryl phosphine and phosphinite ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes are useful as catalysts in asymmetric reactions, such as, hydrogenation, hy
