An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides

DOI: 10.1021/ol0258435

Source and publish data:

Organic Letters p. 1695 - 1698 (2002)

Update date:2022-08-04

Topics:

Authors:

Tang, Wenjun

Chi, Yongxiang

Zhang, Xumu

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Article abstract of DOI:10.1021/ol0258435

Matrix presented An ortho-substituted BIPHEP ligand, o-Ph-hexaMeO-BIPHEP (1), is designed and synthesized. Compared with chiral biaryl phosphines without ortho substituents such as BINAP and MeO-BIPHEP, o-Ph-hexaMeO-BIPHEP shows higher enantioselectivitie

Full text of DOI:10.1021/ol0258435

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