428857-89-0Relevant academic research and scientific papers
Synthesis of 3-O-β-D-glucopyranosyl-(3R)-hydroxybutanolide (Kinsenoside) and 3-O-β-D-glucopyranosyl-(3S)-hydroxybutanolide (Goodyeroside A)
Suzuki, Katsuhiko,Suzuki, Nobuyuki,Yamaura, Masanori,Yoshizawa, Toyokichi
, p. 73 - 84 (2007/10/03)
The first synthesis of 3-O-β-D-glucopyranosyl-(3R)-hydroxybutanolide (Kinsenoside) and 3-O-β-D-glucopyranosyl-(3S)-hydroxybutanolide (Goodyeroside A) is described. The diastereomers of the aglycon in 2-O-β-D-gulucopyranosyl-1,2,4-butanetriol derivatives, which were separable precursors of Kinsenoside and Goodyeroside A, were synthesized from optically nonactive 1,2,4-butanetriol and α-D-glucopyranosyl trichloroacetimidate in excellent yields. Copyright Taylor & Francis, Inc.
