42937-87-1Relevant academic research and scientific papers
A versatile rigid binucleating ligand for Rh2(μ-Cl) 2 moieties (see abstract)
Teixidor, Francesc,Cirera, M. Rosa,Vi?as, Clara,Kivek?s, Raikko,Sillanp??, Reijo,Demonceau, Albert
, p. 89 - 99 (2003)
A rigid non-deforming "MCl2M" binucleating ligand [7,8-μ-S(4′-C6H3(CH3)) S-C2B9H10]- able to held the two rhodium atoms in a cooperative distance has been synthesized. The original two bridging chlorides are retained in [Rh2 (C5Me5)2Cl2{7,8-μ-S (4′-C6H3(CH3))S-C2 B9H10}]+. Hydrogenation of 1-hexene is 10 times faster with [Rh2(C5Me5) 2Cl2{7,8-μ-S(4′-C6H3 (CH3))S-C2B9H10}]+ than with [Rh2(C5Me5)2 Cl4]. A hydrogenation mechanism has been proposed which assumes that [Rh2(C5Me5)2 (Cl)(H){7,8-μ-S(4′-C6H3(CH3)) S-C2B9H10}]+ is the first generated species in the process.
Structure and magnetic properties of a sulfur-nitrogen radical, methylbenzodithiazolyl
McManus,Rawson,Feeder,Palacio,Oliete
, p. 2001 - 2003 (2000)
An X-ray crystal structure of the methylbenzodithiazolyl radical MeC6H3S2N, MBDTA, reveals that it forms a regularly spaced π-stack motif in the solid state; variable temperature magnetic studies show that the susceptibili
Organic Heterocyclothiazenes. Part 3. Synthesis and Structure of 1,3,5,2,4-Trithiadiazepines
Morris, Janet L.,Rees, Charles W.
, p. 211 - 216 (2007/10/02)
1,3λ4δ2,5,2,4-trithiadiazepine (10) has been prepared from 1-chloroethane-1,2-bis(sulphenyl chloride) (11) and bis(trimethylsilyl)sulphurdi-imide (3) and also by dehydrogenation of the 6,7-dihydro derivative (9).Trithiadiazepine (10)
