42976-67-0Relevant articles and documents
Phosphonamidothioic acids as thiophosphonylating agents: Stereochemistry of reactions of N-tert-butyl-P-phenylphosphonamidothioic acid with alcohols
Harger, Martin J.P.,Pater, Christopher
, p. 931 - 932 (1999)
Enantiopure PhP(S)(OH)NHBu(t) reacts with alcohols in CH2Cl2 to give PhP(S)(OH)OR (R = Me, Pr(i), Bu(t)); reaction is completely non-stereospecific with Bu(t)OH and largely so with Pr(i)OH and very low concentrations of MeOH, pointin
Kinetic Facial Selectivity in Nucleophilic Displacements at Tetracoordinate Phosphorus: Kinetics and Stereochemistry in the Reaction of Sodium Ethoxide with O,S-Dimethyl Phenylphosphonothioate
DeBruin, Kenneth E.,Tang, Chen-lan W.,Johnson, David M.,Wilde, Ronnie L.
, p. 5871 - 5879 (2007/10/02)
The reaction of ethoxide ion with O,S-dimethyl phenylphosphonothioate (1a) proceeds with competitive displacements of the methylthio and methoxy ligands.Each displacement occurs with complete inversion of configuration.The two products, ethyl methyl pheny