42984-30-5Relevant academic research and scientific papers
Metal-free syntheses of new azocinesviaaddition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
Arimitsu, Satoru,Genta, Kojya,Mohammadizadeh, Mohammad Reza,Mousavi, S. Hekmat,Poorsadeghi, Samira,Saberi, Dariush
, p. 20552 - 20557 (2020/06/22)
A one-pot, clean and green procedure is described for the syntheses of new azocine derivativesviaaddition reactions of enaminones with acenaphthoquinone followed by periodic acid-mediated oxidative cleavages of the corresponding vicinal diols. Various derivatives of azocine were prepared and well characterized. The excellent yields, simple synthesis procedure, lack of a need to carry out any tedious work-up and column chromatography, metal-free catalysis, and mild reaction conditions are important features of this protocol.
