431-51-6Relevant academic research and scientific papers
Method for preparing 3,3,3-trichloro-1,1,1-trifluoropropane through gas-phase catalytic chlorination
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Paragraph 0032-0043, (2021/06/22)
The invention discloses a method for preparing 3,3,3-trichloro-1,1,1-trifluoropropane through gas-phase catalytic chlorination through gas-phase catalytic chlorination. The method comprises the following step: under the action of a catalyst, subjecting 3,3-dichloro-1,1,1-trifluoropropane and chlorine serving as raw materials to a gas-phase catalytic chlorination reaction in a catalyst bed layer, wherein the catalyst is a molecular sieve, and the molecular sieve is at least one selected from ZSM-5, 5A, MCM-41, a beta type molecular sieve and a Y type molecular sieve. The molecular sieve which is cheap and easy to obtain is used as the catalyst, the reaction is carried out under a gas phase condition, and the method has the advantages of high space time yield, simple process, safe operation, low production cost and the like.
Process for the preparation of 1,1-dichloro-3,3,3-trifluoropropane
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Page/Page column 3, (2008/06/13)
A convenient and economical process for the preparation of 1,1-dichloro-3,3,3-trifluoropropane (HCFC-243) by the reaction of 1,1,1,3,3-pentachloropropane (HCC-240) with hydrogen fluoride in the presence of an activated hydrofluorination catalyst. Also, the selective fluorination of hydrochlorocarbons and/or hydrochlorofluorocarbons, or mixtures thereof is shown. A HCFC-243 reaction product yield of greater than 40% is obtained.
