43123-07-5

Basic information

• Product Name: Acetic acid, trifluoro-, 2-hydroxycyclohexyl ester, trans-
• CAS NO: 43123-07-5
• Molecular Formula: C8H11F3O3
• Molecular Weight: 212.169
• Mol File: 43123-07-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Acetic acid, trifluoro-, 2-hydroxycyclohexyl ester, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, trifluoro-, 2-hydroxycyclohexyl ester, trans-(43123-07-5)
• EPA Substance Registry System: Acetic acid, trifluoro-, 2-hydroxycyclohexyl ester, trans-(43123-07-5)

Safety Data

• Hazardous Substances Data: 43123-07-5(Hazardous Substances Data)

Upstream product

• 286-20-4 cyclohexane-1,2-epoxide 
• 65411-49-6 tetrabutylammonium methanesulfonate 
• 1792-81-0 cis-1,2-cyclohexane 
• 407-25-0 trifluoroacetic anhydride 
• 41049-47-2 trans-1-iodo-2-trifluoroacetoxycyclohexane 
• 359-48-8 trifluoroacetyl peroxide 
• 76-05-1 trifluoroacetic acid 
• 7182-86-7 tetrabutylammonium p-toluenesulfonate 

Downstream Products

• 1228440-23-0 cis-2-(2,2,2-trifluoroacetoxy)cyclohexyl isobutyrate 

Relevant articles and documents

Desymmetrization of meso -1,2-diols via the dynamic kinetic resolution of its monodichloroacetates

Figure presented Enantioselective acylation catalyzed by the thioamide modified 1-methylhistidine methyl ester 1 in combination with DABCO-mediated racemization of the substrate led to the efficient dynamic kinetic resolution of meso-1,2-diol monodichloro

Oxidative Displacement of Hypervalent Iodine from Alkyl Iodides

Oxidative displacement of iodine from primary alkyl iodides and vic-substituted iodocyclohexanes with m-chloroperbenzoic acid in either dichloromethane or t-butyl alcohol-water gives primary alcohols and vic-substituted cyclohexanols, respectively.Retention of configuration at the displacement centre occurs for all of the trans-vic-substituted iodocyclohexanes except the iodoacetate and iodotrifluoroacetate where inversion of configuration occurs to give cis-hydroxy-esters.Oxidation of (S)-2-iodo-octane occurs with almost complete inversion to give (R)-octan-2-ol but also affords octan-1-ol, octan-3-ol, and octan-2-one.