432050-10-7Relevant articles and documents
A new class of ruthenium complexes containing Schiff base ligands as promising catalysts for atom transfer radical polymerization and ring opening metathesis polymerization
De Clercq, Bob,Verpoort, Francis
, p. 67 - 76 (2002)
A novel series of Schiff base ruthenium complexes that are active catalysts in the field of atom transfer radical polymerization (ATRP), have been prepared. Moreover, when activated with trimethylsilyldiazomethane (TMSD), these species exhibit good cataly
METAL COMPLEXES FOR USE IN OLEFIN METATHESIS AND ATOM GROUP TRANSFER REACTIONS
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Page/Page column 75, (2010/02/13)
Improved catalysts useful in a number of organic synthesis reactions such as olefin metathesis and atom or group transfer reactions are made by bringing into contact amulti-coordinated metal complex comprising a multidentate Schiff base ligand, and one or more other ligands, with an acid under conditions such that said acid is able to at least partly cleave a bond between the metal and the multidentate Schiff base ligand of said metal complex, optionally through intermediate protonation of said Schiff base ligand.