433211-61-1

Basic information

• Product Name: C₂₀H₁₇NO₃S₂
• Synonyms: C₂₀H₁₇NO₃S₂
• CAS NO: 433211-61-1
• Molecular Weight: 383.492
• Mol File: 433211-61-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₀H₁₇NO₃S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₁₇NO₃S₂(433211-61-1)
• EPA Substance Registry System: C₂₀H₁₇NO₃S₂(433211-61-1)

Safety Data

• Hazardous Substances Data: 433211-61-1(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 70-11-1 α-bromoacetophenone 

Relevant articles and documents

Preparation of new nitrogen-bridged heterocycles. 53. Syntheses of 3-(benzylthio)thieno[3,4-b]indolizine derivatives and their intramolecular arene-arene interactions.

Various ethyl 1-arylcarbonyl-3-[(un)substituted methylthio]thieno[3,4-b]indolizine-9-carboxylates were synthesized in good yields by a novel methodology in which the S-alkylation of 5-arylcarbonyl-4-ethoxycarbonylmethyl-3-(1-pyridinio)thiophene-2-thiolates with alkyl or benzyl halides, the 1,5-dipolar cyclization of the resulting pyridinium salts in the presence of a base, and the aromatization were performed. In the X-ray analyses of some 3-(benzylthio)thieno[3,4-b]indolizine-9-carboxylates, a gauche and two anti conformers in relation to the exocyclic sulfide linkage were found. Interestingly, all of the 3-(benzylthio)thieno[3,4-b]indolizine derivatives showed significant high-field shifts (delta up to 0.3 ppm) for the 5- and 6-proton signals compared with those of the 3-methylthio derivatives in the (1)H-NMR spectra and exhibited a definite absorption band near 425 nm in their UV spectra, indicating an intramolecular arene-arene interaction between the thieno[3,4-b]indolizine and the phenyl ring.