433732-83-3

Basic information

• Product Name: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate
• Synonyms: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate
• CAS NO: 433732-83-3
• Molecular Weight: 353.483
• Mol File: 433732-83-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate(433732-83-3)
• EPA Substance Registry System: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate(433732-83-3)

Safety Data

• Hazardous Substances Data: 433732-83-3(Hazardous Substances Data)

Upstream product

• 1002-28-4 3-hexyn-1-ol 
• 928-97-2 (E)-3-hexen-1-ol 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 

Downstream Products

• 888488-33-3 5-(but-1-enyl)-1-(p-toluenesulfonyl)-2,3-dihydro-1H-pyrrole 
• 888488-18-4 (E)-N-formyl-N-(hex-3-enyl)-p-toluenesulfonamide 
• 888488-26-4 (E)-N-ethynyl-N-(hex-3-enyl)-p-toluenesulfonamide 
• 888488-22-0 (E)-N-(2,2-dichlorovinyl)-N-(hex-3-enyl)-p-toluenesulfonamide 
• 177972-53-1 N-[(3E)-hex-3-en-1-yl](4-methylphenyl)sulfonamide 

Relevant articles and documents

Zirconium-Mediated Intramolecular Ester Transfer Reaction: Synthesis of α-Substituted γ-Aminobutyric Acid (GABA) Derivatives

(matrix presented) The zirconium-mediated intramolecular ester transfer reaction of N-alkenyl carbamate derivatives proceeded to give α-substituted γ-aminobutyric acid (GABA) derivatives in good to excellent yields. Quenching experiments of the reaction mixture with iodine or O2 indicated the presence of a cyclopropane intermediate. The resulting iodide was converted to 2-substituted pyrrolidine-3-carboxylate and/or α-alkylidene-γ-aminobutyric acid derivatives in a stereospecific manner.

Synthesis of cyclic dienamide using ruthenium-catalyzed ring-closing metathesis of ene-ynamide

Ring-closing metathesis of ene-ynamide, which has alkene and ynamide moieties in a molecule, using a second-generation ruthenium carbene complex produced nitrogen-containing heterocycles, which have a dienamide moiety, in high yields. Diels-Alder reaction

A new, highly stereoselective approach to pyrrolidines via overall 5-endo-trig cyclisations of homoallylic tosylamides

Iodocyclisations of E-homoallylic tosylamides 7 lead to excellent yields of either 2,5-trans- or 2,5-cis-3-iodopyrrolidines (10 or 11), depending upon the reaction conditions.