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1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 433732-83-3 Structure
  • Basic information

    1. Product Name: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate
    2. Synonyms: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate
    3. CAS NO:433732-83-3
    4. Molecular Formula:
    5. Molecular Weight: 353.483
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 433732-83-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate(433732-83-3)
    11. EPA Substance Registry System: 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate(433732-83-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 433732-83-3(Hazardous Substances Data)

433732-83-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 433732-83-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,3,3,7,3 and 2 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 433732-83:
(8*4)+(7*3)+(6*3)+(5*7)+(4*3)+(3*2)+(2*8)+(1*3)=143
143 % 10 = 3
So 433732-83-3 is a valid CAS Registry Number.

433732-83-3Relevant articles and documents

Zirconium-Mediated Intramolecular Ester Transfer Reaction: Synthesis of α-Substituted γ-Aminobutyric Acid (GABA) Derivatives

Ito, Hisanaka,Omodera, Katsunori,Takigawa, Yasushi,Taguchi, Takeo

, p. 1499 - 1501 (2002)

(matrix presented) The zirconium-mediated intramolecular ester transfer reaction of N-alkenyl carbamate derivatives proceeded to give α-substituted γ-aminobutyric acid (GABA) derivatives in good to excellent yields. Quenching experiments of the reaction mixture with iodine or O2 indicated the presence of a cyclopropane intermediate. The resulting iodide was converted to 2-substituted pyrrolidine-3-carboxylate and/or α-alkylidene-γ-aminobutyric acid derivatives in a stereospecific manner.

Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: A rapid approach to diverse azacyclic frameworks

Walker, P. Ross,Campbell, Craig D.,Suleman, Abid,Carr, Greg,Anderson, Edward A.

supporting information, p. 9139 - 9143 (2013/09/12)

I want to ride my azacycle: The title reaction of enynamides affords a wide diversity of azacycles. The reactions are high-yielding, highly stereoselective, and proceed rapidly under mild reaction conditions. Equivalent transformations using enynhydrazides offer new routes to pyrazole and indazole scaffolds. Boc=tert-butoxycarbonyl, EWG=electron-withdrawing group, Ns=4-nitrobenzenesulfonyl, Ts=4-toluenesulfonyl. Copyright

Synthesis of cyclic dienamide using ruthenium-catalyzed ring-closing metathesis of ene-ynamide

Mori, Miwako,Wakamatsu, Hideaki,Saito, Nozomi,Sato, Yukako,Narita, Rie,Sato, Yoshihiro,Fujita, Reiko

, p. 3872 - 3881 (2007/10/03)

Ring-closing metathesis of ene-ynamide, which has alkene and ynamide moieties in a molecule, using a second-generation ruthenium carbene complex produced nitrogen-containing heterocycles, which have a dienamide moiety, in high yields. Diels-Alder reaction

A stereochemically flexible approach to pyrrolidines based on 5-endo-trig iodocyclisations of homoallylic sulfonamides

Jones,Knight,Hibbs

, p. 1182 - 1203 (2007/10/03)

5-endo-trig Iodocyclisations of the (E)-homoallylic sulfonamides 24 in the presence of potassium carbonate give excellent yields of trans-2,5-disubstituted-3-iodopyrrolidines 36. In the absence of base, these initial kinetic products undergo rapid isomeri

A new, highly stereoselective approach to pyrrolidines via overall 5-endo-trig cyclisations of homoallylic tosylamides

Jones, Andrew D.,Knight, David W.

, p. 915 - 916 (2007/10/03)

Iodocyclisations of E-homoallylic tosylamides 7 lead to excellent yields of either 2,5-trans- or 2,5-cis-3-iodopyrrolidines (10 or 11), depending upon the reaction conditions.

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