436151-08-5Relevant academic research and scientific papers
Catalyst-controlled diastereoselective hetero-Diels-Alder reactions
Joly, Guy D.,Jacobsen, Eric N.
, p. 1795 - 1798 (2007/10/03)
The diastereoselective hetero-Diels-Alder reaction between Danishefsky's diene and chiral aldehydes is catalyzed by chiral chromium-Schiff base complexes. High levels of catalyst control are obtained in several cases, allowing access to all four stereoisomeric products through appropriate choice of aldehyde and catalyst enantiomers.
