4362-53-2Relevant articles and documents
Synthesis of dioxolanes and oxazolidines by silica gel catalysis
Rohand, Taoufik,Savary, Jér?me,Markó, István E.
, p. 1429 - 1436 (2018)
Abstract: Ethylene glycol condensed with carbonyl compounds in the presence of silica gel or alumina, without solvent and under pressure, affords 1,3-dioxolanes. 2-Amino-2-methylpropanol also condensed with carbonyl compounds in the presence of silica gel or an acid-activated clay, without solvent and under pressure, produces oxazolidines. To explain these results, we propose that the glycol and the aminopropanol react with Br?nsted (H+) and Lewis acid sites (Si and Al) located on the surface of the catalysts, leading to the products via various ionic intermediates.
Highly efficient acetalization of carbonyl compounds catalyzed by anilin-aldehyde resin salts
Tanemura, Kiyoshi,Suzuki, Tsuneo
supporting information, p. 797 - 799 (2015/06/22)
A mild procedures for the syntheses of ethylene acetals and dimethyl acetals from the corresponding aldehydes and ketones catalyzed by 1mol% of anilinealdehyde resin salts are described. This method is also useful for the synthesis of dimethyl acetals of diaryl ketones.
Highly efficient heterogeneous acetalization of carbonyl compounds catalyzed by a titanium cation-exchanged montmorillonite
Kawabata, Tomonori,Mizugaki, Tomoo,Ebitani, Kohki,Kaneda, Kiyotomi
, p. 8329 - 8332 (2007/10/03)
The titanium cation-exchanged montmorillonite efficiently catalyzed the selective acetalization of various carbonyl compounds as a recyclable solid acid. This heterogeneous catalyst has an advantage of a strikingly simple workup procedure over conventional homogeneous acids.
1,3-Dioxolanes from carbonyl compounds over zeolite HSZ-360 as a reusable, heterogeneous catalyst
Ballini, Roberto,Bosica, Giovanna,Frullanti, Bettina,Maggi, Raimondo,Sartori, Giovanni,Schroer, Frank
, p. 1615 - 1618 (2007/10/03)
Carbonyl compounds are converted, in good yields, into their 1,3-dioxolanes over zeolite HSZ-360, as a new reusable catalyst. Good chemoselectivity is also observed.
A Selectivity Study of Activated Ketal Reduction with Borane Dimethyl Sulfide
Bartels, Birgit,Hunter, Roger
, p. 6756 - 6765 (2007/10/02)
A chemo- and regioselectivity study of the reagent combination BH3*SMe2/TMSOTf for ketal reduction has been undertaken.It has revealed that simple 1,3-dioxanes reduce cleanly at low temperature in CH2Cl2 while simple 1,3-dioxolanes may give complete ring cleavage and dimerization products.A study of reduction of 4-substituted 1,3-dioxolanes has revealed a solvent-directed regioselectivity which in THF favors the secondary protected derivative.A mechanism is postulated to account for the selectivities based on recent thinking on acetal substitution reactions.
N-(arylmethyl)-2-(or -4)-cyanopyridinium hexafluoroantimonates as new useful catalysts for acetalization of carbonyl compounds
Lee,Lee,Takata,Endo
, p. 368 - 370 (2007/10/02)
Carbonyl compounds 1 were converted to the corresponding 1,3-dioxolanes 2 and 1,3-dioxanes 4 with ethylene glycol and 2,2-dimethyl-1,3-propandiol, respectively, in the presence of 1-3 mol% of N-(benzyl, 4-methylbenzyl or 4-methoxybenzyl)-2(or -4)cyanopyridinium hexafluoroantimonates 3. The catalyst 3d was also effective for the tetrahydropyranylation.
Magnetic Isotope Effects in Photochemical Reactions. Observation of Carbonyl 17O Hyperfine Coupling to Phenylacetyl and Benzoyl Radicals. 17O-Enrichment Studies
Turro, Nicholas J.,Paczkowski, Mark A.,Wan, Peter
, p. 1399 - 1404 (2007/10/02)
The photochemistry of 17O-enriched (at C=O) dibenzyl ketone (DBK), benzoin methyl ether (BME), and deoxybenzoin (DB) has been studied on porous silica and in homogeneous solution with the aim of enriching the recovered ketones with 17O separation of magn
