436853-30-4Relevant academic research and scientific papers
Photoinduced electron transfer quenching and sugar effects on the electrostatic interaction between an anionic Ru(II) complex and cationic bipyridinium derivatives functionalized with boronic acids
Uddin, Md. Jamal,Dicesare, Nicolas,Lakowicz, Joseph R.
, p. 104 - 110 (2012)
The photoinduced electron transfer quenching of an anionic ruthenium(II) metal-ligand-complex (Ru(dpp(SO3Na))2(mcbpy)Cl2 by two boronic acid functionalized benzyl viologen (BV2+) derivatives has been investigated as well as their response to sugar. The electrostatic interaction between these two charge species lead to the formation of static quenching which is removed in presence of sugar due to the formation of a neutral zwitterionic quencher. Spectral data, quenching parameters and sugar titration curves are presented and discussed in term of future developments of optical sensors for sugar.
A facile channel for D-glucose detection in aqueous solution
Wang, Zhijun,Lei, Haiying,Feng, Liheng
, p. 293 - 297 (2013/11/19)
Three facile ensembles for sensing D-glucose are designed and constructed. The ensembles are comprised of fluorescent dye (NAHBDS) and boronic acid substituted viologens (BBVs) quenchers/receptors. The sensing processes of three ensembles (NAHBDS/o-BBV, NAHBDS/m-BBV and NAHBDS/p-BBV) to D-glucose were determined by fluorescence spectra at pH 7.4 buffer solution. The results show that NAHBDS/o-BBV and NAHBDS/m-BBV ensembles embody higher sensitivity for D-glucose with reversible "on-off" fluorescence response. More importantly, the recovery of relative intensity has good linear relation to low concentration of D-glucose. The action between the ensemble with D-glucose is dynamically reversible equilibrium process. The research results provide a new mode to design highly selective probe.
Highly selective ensembles for D-fructose based on fluorescent method in aqueous solution
Wang, Zhijun,Lei, Haiying,Zhou, Chengyong,Wang, Guofeng,Feng, Liheng
, p. 178 - 183 (2012/05/07)
Three highly sensitive and selective switches for monosaccharides were composed by anionic polyelectrolyte PPPSO3Na and cationic viologen quencheres BBVs. The sensing processes of three ensembles (PPPSO 3Na/o-BBV, PPPSO3Na/m-BBV and PPPSO3Na/p-BBV) to common seven monosaccharides have been determined by fluorescence spectra at pH 7.4 buffer solution. The results show that the three sensing ensembles all embody higher selectivity and sensitivity for d-fructose with reversible "on-off-on" fluorescence response. The research results can provide a new mode for developing highly selective probes.
The effect of boronic acid-positioning in an optical glucose-sensing ensemble
Gamsey, Soya,Baxter, Nichol A.,Sharrett, Zachary,Cordes, David B.,Olmstead, Marilyn M.,Wessling, Ritchie A.,Singaram, Bakthan
, p. 6321 - 6331 (2007/10/03)
The quenching of the anionic dye 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt (pyranine) with three different boronic acid-substituted benzyl viologens was determined, and the fluorescence signal modulation obtained upon addition of glucose to th
