4376-72-1Relevant academic research and scientific papers
A POSS-Phosphazene Based Porous Material for Adsorption of Metal Ions from Water
Soldatov, Mikhail,Liu, Hongzhi
, p. 4345 - 4351 (2019)
The development of adsorptive materials continues to be an important area of research for removal of heavy metal ions from waste water. The adsorption capacity can be modulated by both physical and chemical modification of the adsorbent. Herein, we combin
Synthesis and characterization of new (dimethylsilyl)phenoxy and (dimethyl(vinyl)silyl)phenoxy substituted cyclotriphosphazenes
Januszewski, Rafa?,Dutkiewicz, Micha?,Kubicki, Maciej,Dutkiewicz, Grzegorz,Maciejewski, Hieronim,Marciniec, Bogdan
, p. 64 - 67 (2017)
The routes of synthesis, as well as, spectroscopic and X-ray diffraction characterization of a new group of bis- or hexakis-4-(dimethyl(vinyl)silyl)phenoxy and 4-(dimethylsilyl)phenoxy-substituted cyclotriphosphazenes as a versatile starting substrates for the synthesis of a variety of organic cyclophosphazene derivatives, via catalytic hydrosilylation or silylative coupling processes, is presented.
Pd complexes based on phosphine-linked cyclophosphazenes: Synthesis, characterization and application in suzuki coupling reactions
De Paula, Vanderlei I.,Sato, Cintia A.,Buffon, Regina
experimental part, p. 258 - 266 (2012/05/05)
Palladium complexes were obtained by reaction of phosphine-linked cyclophosphazenes, (P3N3)(O-C6H 4-PR2)6, where R = phenyl, i-propyl or cyclohexyl, with using a Pd/ligand molar ratio of 3/1. The (P3N 3)(O-C6H4-PR2)6Pd 3(dba)x complexes were characterized by elemental analyses, mass spectrometry, 31P NMR and FT-IR where a characteristic nC=C band of dba coordinated to palladium was always observed. All complexes were tested in Suzuki coupling reactions between phenylboronic acid and aryl halides. Turnover numbers as high as ca. 17,500 for the coupling of 2-bromotoluene with chlorophenylboronic acid could be obtained for R = cyclohexyl. The complex based on -PPh2 was also immobilized in silica matrixes by the sol-gel method. Preliminary experiments showed that the immobilized catalyst could be used in at least three consecutive Suzuki reactions with the same catalytic activity.
