437609-55-7Relevant academic research and scientific papers
Stereoselective synthesis of 2-epi-jaspine B via base-catalyzed intramolecular oxy-Michael conjugate addition approach
Reddipalli, Gowrisankar,Venkataiah, Mallam,Mishra, Mithilesh Kumar,Fadnavis, Nitin W.
experimental part, p. 1802 - 1805 (2009/12/26)
2-epi-Jaspine B has been synthesized starting from (-)-diethyl tartrate in 12 simple steps and 26.6% overall yield. The key intermediate was obtained via stereoselective base-catalyzed intramolecular oxy-Michael conjugate addition followed by tandem hydro
Synthesis of D-erythro-dihydrosphingosine and D-xylo-phytosphingosine from a serine-derived 1,5-dioxaspiro[3.2]hexane template
Ndakala, Albert J.,Hashemzadeh, Mehrnoosh,So, Regina C.,Howell, Amy R.
, p. 1719 - 1722 (2007/10/03)
Matrix presented A serine-derived 1,5-dioxaspiro[3.2]hexane template is shown to be a useful precursor for both aminodiol and aminotriol sphingoid bases by its conversion to D-erythro-dihydrosphingosine and D-xylo-phytoshingosine.
