438252-53-0Relevant academic research and scientific papers
Genenation of 1-azapentadienyl anion from N-(tert-butyldimethylsilyl)-3-buten-1-amine
Jacobson, Madeleine A.,Williard, Paul G.
, p. 3915 - 3918 (2002)
N-(tert-Butyldimethylsilyl)-3-buten-1-amine undergoes allylic deprotonation at the 2-position when exposed to 2 equiv of nBuLi in THF. This allylic anion undergoes lithium hydride elimination to generate a 1-azapentadienyl anion. The anion is generated cleanly and completely.
