4383-66-8Relevant academic research and scientific papers
Method for producing alcoxylated carbonyl compounds by an anodic oxidation method using a cathodic coupled reaction for organic synthesis
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Page column 5, (2008/06/13)
A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R1aR2C(OR3)bwherein R1, R2represent hydrogen or C1-C6-alkyl, R3independently means C1-C6-alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R4, R5, R6, R7represent hydrogen or C1-C6-alkyl, R5, R6represent C1-C6-alkyl or C1-C6-alcoxy, in the presence of a C1-C6-alkyl alcohol (compounds III). A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C1-C6-alkyl alcohols.
