439213-17-9

Upstream product

• 439290-17-2 methyl (S,S)-5,6-bis(tert-butyldimethylsilanyloxy)cyclohexa-1,3-dienecarboxylate 
• 176487-06-2 (2S,3S)-(+)-trans-2,3-dihydroxy-2,3-dihydrobenzoic acid 

Downstream Products

• 439213-21-5 Benzoic acid (1S,2R,4R,5R,6S,7R)-5,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,8-dioxa-tricyclo[5.1.0.0^2,4]oct-4-ylmethyl ester 
• 439290-20-7 benzoic acid 5,6-dihydroxy-3,8-dioxatricyclo[5.1.0.0^2,4]oct-4-ylmethyl ester 

Relevant academic research and scientific papers

Cyclohexadiene-trans-diols as versatile starting material in natural product synthesis: Short and efficient synthesis of iso-crotepoxide and ent-senepoxide

A new synthesis of ent-senepoxide and iso-crotepoxide starting from microbially produced (+)-trans-2,3-dihydroxy-2,3-dihydrobenzoic acid via regio- and stereoselective epoxidation is described.