439290-17-2

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 439213-14-6 (5S,6S)-methyl 5,6-dihydroxycyclohexa-1,3-dienecarboxylate 
• 176487-06-2 (2S,3S)-(+)-trans-2,3-dihydroxy-2,3-dihydrobenzoic acid 

Downstream Products

• 623163-88-2 methyl (3R,4R,5S,6S)-5,6-bis(tert-butyldimethylsilanyloxy)-3,4-dihydroxycyclohex-1-enecarboxylate 
• 623163-89-3 (1R,2R,5S,6S)-5,6-bis(tert-butyldimethylsilanyloxy)-4-hydroxymethylcyclohex-3-ene-1,2-diol 
• 439290-20-7 benzoic acid 5,6-dihydroxy-3,8-dioxatricyclo[5.1.0.0^2,4]oct-4-ylmethyl ester 
• 439213-21-5 Benzoic acid (1S,2R,4R,5R,6S,7R)-5,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,8-dioxa-tricyclo[5.1.0.0^2,4]oct-4-ylmethyl ester 
• 439213-17-9 [(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-cyclohexa-1,3-dienyl]-methanol 

Relevant academic research and scientific papers

(S,S)-2,3-dihydroxy-2,3-dihydrobenzoic acid: Microbial access with engineered cells of Escherichia coli and application as starting material in natural-product synthesis

Cyclohexadiene-trans-5,6-diols such as (S,S)-2,3-dihydroxy-2,3-dihydrobenzoic acid (2,3-trans-CHD) have been shown to be of importance as chiral starting materials for the syntheses of bioactive substances, especially for the syntheses of carbasugars. By

Cyclohexadiene-trans-diols as versatile starting material in natural product synthesis: Short and efficient synthesis of iso-crotepoxide and ent-senepoxide

A new synthesis of ent-senepoxide and iso-crotepoxide starting from microbially produced (+)-trans-2,3-dihydroxy-2,3-dihydrobenzoic acid via regio- and stereoselective epoxidation is described.