4393-11-7

Basic information

• Product Name: Benzenemethanamine, N-(2-furanylmethylene)-
• CAS NO: 4393-11-7
• Molecular Formula: C12H11NO
• Molecular Weight: 185.225
• Mol File: 4393-11-7.mol
• Article Data: 51

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-(2-furanylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-(2-furanylmethylene)-(4393-11-7)
• EPA Substance Registry System: Benzenemethanamine, N-(2-furanylmethylene)-(4393-11-7)

Safety Data

• Hazardous Substances Data: 4393-11-7(Hazardous Substances Data)

Upstream product

• 98-00-0 (2-furyl)methyl alcohol 
• 100-46-9 benzylamine 
• 69819-61-0 N-(furan-2-ylmethylene)cyclohexanamine 
• 98-01-1 furfural 
• 10354-48-0 furan-2-carboxylic acid benzylamide 
• 27046-29-3 N-(4-bromobenzylidene)benzylamine 
• 1361111-11-6 C₁₆H₁₃⁽²⁾H₂BrN₂ 
• 1361110-35-1 methyl 3-(benzylamino)-2,2-dideutero-3-(4-bromophenyl)propanoate 

Downstream Products

• 129823-56-9 (2S,3R)-3-Benzylamino-3-furan-2-yl-2-methyl-propionic acid methyl ester 
• 129823-56-9 (2R,3R)-3-Benzylamino-3-furan-2-yl-2-methyl-propionic acid methyl ester 
• 93965-61-8 benzyl[1-(furan-2-yl)but-3-en-1-yl]amine 
• 93965-62-9 Benzyl-(1-furan-2-yl-2-methyl-but-3-enyl)-amine 
• 142054-93-1 Ethyl N-benzyl-N-carbamate 
• 1361110-39-5 C₁₅H₁₅⁽²⁾H₂NO₃ 
• 1361111-15-0 C₁₄H₁₂⁽²⁾H₂N₂O 
• 69819-61-0 N-(furan-2-ylmethylene)cyclohexanamine 
• 129082-21-9 methyl 2(S)-<(R)-benzenemethylamino-(furan-2-yl)methyl>-3(R)-hydroxybutyrate 
• 33542-84-6 N-(1,2-diphenyl-ethyl)-N-benzylamine 
• 101202-06-6 4-benzyl-5-furan-2-yl-1,3-diphenyl-4,5-dihydro-1H-[1,2,4]triazole 

Relevant articles and documents

Enantioselective Reductive Cyanation and Phosphonylation of Secondary Amides by Iridium and Chiral Thiourea Sequential Catalysis

The combination of transition-metal catalysis and organocatalysis increasingly offers chemists opportunities to realize diverse unprecedented chemical transformations. By combining iridium with chiral thiourea catalysis, direct enantioselective reductive cyanation and phosphonylation of secondary amides have been accomplished for the first time for the synthesis of enantioenriched chiral α-aminonitriles and α-aminophosphonates. The protocol is highly efficient and enantioselective, providing a novel route to the synthesis of optically active α-functionalized amines from the simple, readily available feedstocks. In addition, the reactions are scalable and the thiourea catalyst can be recycled and reused.

A designed and potentially decadentate ligand for use in lanthanide(iii) catalysed biomass transformations: Targeting diastereoselective: Trans -4,5-diaminocyclopentenone derivatives

The goal of this study was to design a ligand system which can accommodate single lanthanide(iii)-ions and investigate the properties of the resulting complexes. The complexes of all the accesible lanthanides and yttrium with the new ligand LH6 = N,N′-dimethyl-N,N′-ethylene-bis(5-bromo-3-(1H-benzimidazol-2-yl)hydrazineylidene)-2-hydroxybenzylamine) were obtained in high yield at room temperature under aerobic reaction conditions. The corresponding compounds were characterised using X-ray diffraction, FT-IR, elemental analysis and the optical properties of all complexes were investigated using UV-vis and fluorescence spectroscopy. The air stable complexes efficiently transform biomass furfural to trans-4,5-cyclopentenones in high yield.

Improving C=N bond reductions with (Cyclopentadienone)iron complexes: Scope and limitations

Herein, we broaden the application scope of (cyclo-pentadienone)iron complexes 1 in C=N bond reduction. The catalytic scope of pre-catalyst 1b, which is more active than the “Kn?lker complex” (1a) and other members of its family, has been expanded to the catalytic transfer hydrogenation (CTH) of a wider range of aldimines and ketimines, either pre-isolated or generated in situ. The kinetics of 1b-promoted CTH of ketimine S1 were assessed, showing a pseudo-first order profile, with TOF = 6.07 h–1 at 50 % conversion. Moreover, the chiral complex 1c and its analog 1d were employed in the enantioselective reduction of ketimines and reductive amination of ketones, giving fair to good yields and moderate enantioselectivity.