440122-04-3Relevant articles and documents
Safe radical azidonation using polystyrene supported diazidoiodate(I)
Marinescu, Lavinia Georgeta,Pedersen, Christian Marcus,Bols, Mikael
, p. 123 - 127 (2005)
Aldehydes are converted to acyl azides and benzyl ethers to azido ethers by treatment with polymer supported iodine azide in MeCN at 83°C. The reaction provides a safe and convenient alternative to the use of iodine azide in radical azidonations. Graphical Abstract.
Substitution of α-azido ethers with Grignard reagents and its use in combinatorial chemistry
Baruah, Mukulesh,Bols, Mikael
, p. 509 - 512 (2007/10/03)
α-Azidobenzyl ethers were reacted with alkyl or arylGrignard reagents in toluene to produce α-alkylbenzyl or diarylmethyl ethers in 82-94% yield. α-Azidobenzyl ethers were also reacted with multicomponent Grignard reagents to produce libraries of α-alkylbenzyl ethers.