440677-04-3Relevant academic research and scientific papers
Asymmetric construction of the azaspiro[5.5]undec-8-ene system towards gymnodimine synthesis
Tsujimoto, Takashi,Ishihara, Jun,Horie, Mariko,Murai, Akio
, p. 399 - 402 (2007/10/03)
In the course of the synthetic studies on gymnodimine, a potent shellfish toxin, the asymmetric construction of the azaspirocyclic part was achieved by the (-)-siam·Cu(SbF6)2 complex catalyzed intermolecular Diels-Alder reaction in high exo- and enantioselectivities.
