441017-58-9Relevant academic research and scientific papers
Regioselective acetolysis of highly O-benzylated carbohydrates promoted by iodine or an iodine/silane combined reagent: Use of isopropenyl acetate as an alternative to acetic anhydride
Giordano, Maddalena,Iadonisi, Alfonso,Pastore, Antonello
, p. 3137 - 3147 (2013/06/27)
Regioselective acetolytic de-O-benzylation of poly-O-benzylated sugars can be triggered by the activation of isopropenyl acetate (IPA) with either an iodine/silane combined reagent or iodine alone. Unlike other known acetolysis procedures, the protocols p
Solution- and solid-phase oligosaccharide synthesis using glucosyl iodides: a comparative study
Lam, Son N.,Gervay-Hague, Jacquelyn
, p. 1952 - 1966 (2007/10/03)
Glycosyl iodide donors have been used in both solid- and solution-phase syntheses yielding α-(1->6)-linked glucosyl oligomers in highly efficient protocols. While the solid-phase strategy offers advantages in terms of ease of purification, it requires a t
Solution-Phase Hexasaccharide Synthesis Using Glucosyl Iodides
Lam, Son N.,Gervay-Hague, Jacquelyn
, p. 2039 - 2042 (2007/10/03)
(Equation Presented) Oligosaccharides composed of 1,6-glucosyl residues have been prepared from glucosyl iodides. The reactions are highly stereoselective, giving the α-glycosides as the only isolated products in yields ranging from 84% to 94%. Oligomer s
