443095-50-9Relevant academic research and scientific papers
From p-benzoquinone to useful chiral cyclohexane building blocks
Busque, Felix,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 3077 - 3080 (2001)
A straightforward and efficient access to 12 new cyclohexane chirons from an easily available enantiopure monoketal of p-benzoquinone is described. These chirons possess a variety of functional groups which render them useful for further synthetic elabora
From p-benzoquinone to cyclohexane chirons: First asymmetric synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide
Busque, Felix,Canto, Mariona,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 2021 - 2032 (2007/10/03)
Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes.
