443123-83-9Relevant academic research and scientific papers
Asymmetric total synthesis of the myxobacteria metabolites crocacins A-D
Feutrill, John T.,Lilly, Michael J.,White, Jonathan M.,Rizzacasa, Mark A.
, p. 4880 - 4895 (2008/09/21)
The total syntheses of crocacins A-D are described. The key steps were a syn-aldol reaction followed by anti-reduction to secure the stereotetrad and acylation of an ene- or dienecarbamate to form the enamide. Crown Copyright
Total synthesis of (+)-crocacin D
Chakraborty, Tushar K,Laxman, Pasunoori
, p. 2645 - 2648 (2007/10/03)
The first total synthesis of the potent antifungal and cytotoxic agent (+)-crocacin D in optically pure form following a convergent strategy is described here. The regioselective ring opening of a silyl-substituted epoxide with an azide ion, based on a me
