4432-43-3

Basic information

• Product Name: 4-Morpholinemethanol
• Synonyms: 4-Morpholinemethanol;morpholin-4-ylmethanol
• CAS NO: 4432-43-3
• Molecular Formula: C₅H₁₁NO₂
• Molecular Weight: 117.15
• Mol File: 4432-43-3.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 190.8°Cat760mmHg
• Flash Point: 69.2°C
• Appearance: /
• Density: 1.093g/cm³
• Vapor Pressure: 0.143mmHg at 25°C
• Refractive Index: 1.469
• PKA: 14.39±0.10(Predicted)
• CAS DataBase Reference: 4-Morpholinemethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Morpholinemethanol(4432-43-3)
• EPA Substance Registry System: 4-Morpholinemethanol(4432-43-3)

Safety Data

• Hazardous Substances Data: 4432-43-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C5H11NO2/c7-5-6-1-3-8-4-2-6/h7H,1-5H2

Upstream product

• 110-91-8 morpholine 
• 50-00-0 formaldehyd 
• 536-74-3 phenylacetylene 
• 3773-84-0 β-morpholinyl-N,N-morpholinylpropionic acid amide 
• 5625-90-1 4-(morpholinomethyl)morpholine 

Downstream Products

• 15622-65-8 molindone hydrochloride 
• 110-91-8 morpholine 
• 463-57-0 methanediol 
• 1834-41-9 2-(4-isopropoxy-phenyl)-5-morpholin-4-ylmethyl-3H-[1,3]thiazine-4,6-dione 
• 1695-55-2 2-(3,4-dimethyl-phenyl)-5-morpholin-4-ylmethyl-[1,3]thiazine-4,6-dione 
• 1697-29-6 5-morpholin-4-ylmethyl-2-(3,4,5-trimethoxy-phenyl)-3H-[1,3]thiazine-4,6-dione 
• 20894-04-6 5-morpholin-4-ylmethyl-2,3-diphenyl-5,6,7,8-tetrahydro-1H-cyclohepta[b]pyrrol-4-one 
• 15884-74-9 4-hydroxy-3-morpholin-4-ylmethyl-1-phenyl-5,6,7,8-tetrahydro-1H-quinolin-2-one 
• 20894-02-4 3-ethyl-5-morpholin-4-ylmethyl-2-phenyl-5,6,7,8-tetrahydro-1H-cyclohepta[b]pyrrol-4-one 
• 1695-52-9 2-(4-chloro-phenyl)-5-morpholin-4-ylmethyl-[1,3]thiazine-4,6-dione 
• 5657-22-7 morpholinomethylurea 
• 2224-44-4 4-(2-nitrobutyl)morpholine 
• 81104-52-1 4,4'-(2-nitropropane-1,3-diyl)dimorpholine 
• 6857-12-1 N-morpholin-4-ylmethyl-phthalimide 

Relevant articles and documents

Process for Productions of Formamides and Acrylamides

This invention relates to performance chemicals field, it discloses a novel and green process for simultaneous productions of formamides as well as mono- and multi-functional acrylamides under very mild conditions and with high efficiency. These substances are widely useful as industrial solvents or raw materials, in particular acrylamides are important olefinically-unsaturated polymerizable monomers in photo-curing materials.

Preparation of (S')-3,3,-bis-morpholinomethyl- 5,5',6,6',7,7',8,8'- octahydro-1,1,-BI-2-naphthol

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Tocopherols by hydride reduction of dialkylamino derivatives

Aminomethylation with Mannich reagents derived from secondary amines and paraformaldehyde under improved conditions has been used to convert non-α-tocopherol homologues into α-tocopherol, the biologically most important vitamin E compound. Mono- and bis(aminomethylated) β-, γ-and δ-tocopherol were then subsequently transformed into the corresponding tocopherols (α- and β-tocopherol) by reductive deamination. As an alternative to classical catalytic hydrogenation in the last step, efficient laboratory protocols using complex hydrides have been derived and applied to the preparation of labelled vitamin E compounds. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.