443299-18-1

Upstream product

• 120692-80-0 3-azidobenzyl chloride 
• 89937-85-9 1-azido-3-hydroxymethylbenzene 
• 1877-77-6 3-aminobenzenemethanol 

Downstream Products

• 443299-12-5 bis-(3-azido-benzyl)-[1-(3-azido-phenyl)-ethyl]-amine 
• 443299-13-6 C₆₃H₅₉N₁₀P₃ 
• 443299-10-3 tris(3-azidobenzyl)amine 
• 902140-68-5 C₆₂H₅₅BrClN₁₀P₃ 
• 902140-70-9 C₆₄H₆₁N₁₀P₃ 
• 902140-59-4 tris(m-azidobenzyl)amine 
• 902140-53-8 N-(3-azidobenzyl)-N-(5-azido-2-bromobenzyl)-N-(5-azido-2-chlorobenzyl)amine 
• 902140-65-2 N,N-bis(3-azido-4-methylbenzyl)-N-(3-azidobenzyl)amine 
• 902140-79-8 N,N-bis(3-azidobenzyl)-N-[2-(2-azidophenyl)ethyl]amine 

Relevant academic research and scientific papers

Center-to-propeller and propeller-to-propeller stereocontrol in a series of macrobicyclic tri-λ5-phosphazenes

Center-to-propeller stereocontrol in a family of macrobicyclic, double-propeller shaped tri-λ5-triphosphazenes remains constant in the upper tribenzylamine fragment as the size of the pivotal group at the lower tris(phosphane) fragment is gradu

New macrobicyclic triphosphazides and triphosphazenes formed by self-assembly of tripodal triazides with triphosphanes

The self-assembly of tris(3-azidobenzyl)amines with 1,1,1-tris[(diphenylphosphino)methyl]ethane via tripod-tripod coupling proceeds successfully to give chiral macrobicyclic triphosphazides. The heating of these macrobicyclic cages induces a remarkable stepwise triple extrusion of molecular nitrogen to afford tri-λ5-phosphazenes, which preserved the chiral, propeller-like topology of their precursors. The replacement of one benzylic arm by an ortho-phenethylic or propylenic one still allows the success of the self-assembly. However, the quaternization of the pivotal nitrogen atom of the triamine in the form of N-oxide prevented its coupling with the triphosphane.