443754-68-5Relevant academic research and scientific papers
FeCl3-Catalyzed oxidative allylation of sp2 and sp3 C-H bond adjacent to a nitrogen atom: Easy access to homoallyl tertiary amines
Kumaraswamy, Gullapalli,Murthy, Akula Narayana,Pitchaiah, Arigala
supporting information; experimental part, p. 3916 - 3919 (2010/07/05)
Figure presented Oxidative allylation to sp2- and sp 3-carbon attached to the nitrogen atom was accomplished. The α-allylation of tertiary amines was catalyzed by easily available hydrated iron(III) chloride in combination with air or aqueous tBuOOH. Remarkably, N-allyl- and N-propagyl-tethered tertiary amines were also allylated through this protocol.
