443883-74-7

Basic information

• Product Name: Cyclohexanol, 5-methyl-2-(1-methylethylidene)-, (5R)-
• CAS NO: 443883-74-7
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 443883-74-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 5-methyl-2-(1-methylethylidene)-, (5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 5-methyl-2-(1-methylethylidene)-, (5R)-(443883-74-7)
• EPA Substance Registry System: Cyclohexanol, 5-methyl-2-(1-methylethylidene)-, (5R)-(443883-74-7)

Safety Data

• Hazardous Substances Data: 443883-74-7(Hazardous Substances Data)

Upstream product

• 89-82-7 pulegone 
• 75-05-8 acetonitrile 

Downstream Products

• 183620-24-8 [(3R,4R)-3-(2-Furan-3-yl-ethyl)-3,4-dimethyl-cyclohex-1-enyloxy]-trimethyl-silane 
• 183620-22-6 [(3S,4R)-3-(2-Furan-3-yl-ethyl)-4-methyl-cyclohex-1-enyloxy]-trimethyl-silane 
• 183620-23-7 (4R)-(+)-3-[2-(3-furyl)ethyl]-4-methylcyclohex-2-en-1-one 
• 75337-05-2 (+)-(R)-4-methyl-2-cyclohexene-1-one 
• 59805-78-6 (-)-5R,6R-microcionin-2 
• 24302-23-6 (4R)-1-(1-hydroxy-1-methylethyl)-4-methylcyclohexene 

Relevant articles and documents

(1R,5R)-1-(1-dimethylaminoethyl)-2-isopropylidene-5-methylcyclohexanol as a chiral ligand in the enantioselective addition of diethylzinc to aldehydes

An efficient chiral ligand, (1R,5R)-1-(1-dimethylaminoethyl)-2- isopropylidene-5-methylcyclohexanol, has been developed for the enantioselective addition of diethylzinc to some prochiral aldehydes to afford S-alcohols. The overall conversion rate was 80-98% with excellent enantiomeric excess (79-98%). Georg Thieme Verlag Stuttgart ? New York.

The first enantioselective synthesis of (-)-microcionin 2

An approach known to give regiospecific and stereospecific reactions has been applied to the enantioselective synthesis of the natural (-)-microcionin 2 (1), a prototype of trans relationship of the methyl groups on the furanosesquiterpenes.