444026-69-1

Basic information

• Product Name: [Mn((C(C₆H₅)CCHCHCN)3C(C₆H₅)CCHNHCC)(C₄H₈O)]
• CAS NO: 444026-69-1
• Molecular Weight: 739.778
• Mol File: 444026-69-1.mol

Chemical Properties

• CAS DataBase Reference: [Mn((C(C₆H₅)CCHCHCN)3C(C₆H₅)CCHNHCC)(C₄H₈O)](CAS DataBase Reference)
• NIST Chemistry Reference: [Mn((C(C₆H₅)CCHCHCN)3C(C₆H₅)CCHNHCC)(C₄H₈O)](444026-69-1)
• EPA Substance Registry System: [Mn((C(C₆H₅)CCHCHCN)3C(C₆H₅)CCHNHCC)(C₄H₈O)](444026-69-1)

Safety Data

• Hazardous Substances Data: 444026-69-1(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 

Relevant articles and documents

Metal oxidation promoted C-H activation in manganese complexes of N-confused porphyrin

The N-confused porphyrin complex MnII(NCHPP)Br exhibits a nonplanar porphyrin ring with an inner core C-H on the inverted pyrrole ring. The aerobic metal oxidation promotes the dissociation of an inner-core proton on the inverted pyrrole ring and changes the N-confused porphyrin conformation to a planar porphyrin ring to form MnII(NCPP)Br. The conjugate systems and metal oxidation states are confirmed by crystal structures as well as spectroscopic data. The reverse reaction can be achieved by treating the MnII(NCPP)Br with p-toluenesulfonhydrazide.