444716-99-8Relevant academic research and scientific papers
Construction of C-nucleosides diversified by [3+2] cycloaddition from a sugar-based mesoionic ring
Arévalo, María J.,ávalos, Martín,Babiano, Reyes,Cintas, Pedro,Jiménez, José L.,Light, Mark E.,Palacios, Juan C.
, p. 6909 - 6917 (2007/10/03)
A mesoionic acyclic C-nucleoside (4), serves as the starting chiron to construct highly functionalized 2-aza-7-thiabicyclo[2.2.1]heptanes and heptenes by means of a [3+2] cycloaddition with acetylenic and olefinic dipolarophiles. Further elimination of ei
Generation and fate of a novel homochiral mesoionic dipole: Synthesis of C-nucleoside analogs
Arevalo, Maria J.,Avalos, Martin,Babiano, Reyes,Cintas, Pedro,Hursthouse, Michael B.,Jimenez, Jose L.,Light, Mark E.,Palacios, Juan C.
, p. 223 - 226 (2007/10/03)
A mesoionic acyclic C-nucleoside 4, generated readily from δ-gluconolactone in a few synthetic steps, serves as the chiral core to construct a series of functionalized nucleosides bearing 2-aza-7-thiabicycle[2.2.1]heptane or 2-(1H)-pyridone moieties as th
