444716-98-7

Upstream product

• 2912-62-1 α-chlorophenylacetyl chloride 
• 289678-02-0 2,3,4,5,6-penta-O-acetyl-N-methyl-D-thiogluconamide 
• 147964-50-9 2,3,4,5,6-penta-O-acetyl-N-methyl-D-gluconamide 

Downstream Products

• 444716-99-8 (3aS,4S,7R,7aR)-4-(1',2',3',4',5'-penta-O-acetyl-D-gluco-pentitol-1-yl)-4,7-epithio-2,3a,4,4,7,7a-hexahydro-5-methyl-2,7-diphenyl-1H-pyrrolo[3,4-c]pyridine-1,3,6-trione 
• 444717-00-4 (3aR,4R,7S,7aS)-4-(1',2',3',4',5'-penta-O-acetyl-D-gluco-pentitol-1-yl)-4,7-epithio-2,3a,4,4,7,7a-hexahydro-5-methyl-2,7-diphenyl-1H-pyrrolo[3,4-c]pyridine-1,3,6-trione 
• 444717-06-0 (1R,4S,5S)-1-(1',2',3',4',5'-penta-O-acetyl-D-glucopentitol-1-yl)-2-aza-5-cyano-2-methyl-3-oxo-4-phenyl-7-thiabicyclo[2.2.1]heptane 
• 444717-05-9 (1S,4R,5R)-1-(1',2',3',4',5'-penta-O-acetyl-D-glucopentitol-1-yl)-2-aza-5-cyano-2-methyl-3-oxo-4-phenyl-7-thiabicyclo[2.2.1]heptane 
• 905705-33-1 (1R,4R)-1-(1',2',3',4',5'-penta-O-acetyl-D-gluco-pentitol-1-yl)-2-aza-2-methyl-5,6-dimethoxycarbonyl-3-oxo-4-phenyl-7-thiabicyclo[2.2.1]hept-5-ene 

Relevant academic research and scientific papers

Construction of C-nucleosides diversified by [3+2] cycloaddition from a sugar-based mesoionic ring

A mesoionic acyclic C-nucleoside (4), serves as the starting chiron to construct highly functionalized 2-aza-7-thiabicyclo[2.2.1]heptanes and heptenes by means of a [3+2] cycloaddition with acetylenic and olefinic dipolarophiles. Further elimination of ei

Generation and fate of a novel homochiral mesoionic dipole: Synthesis of C-nucleoside analogs

A mesoionic acyclic C-nucleoside 4, generated readily from δ-gluconolactone in a few synthetic steps, serves as the chiral core to construct a series of functionalized nucleosides bearing 2-aza-7-thiabicycle[2.2.1]heptane or 2-(1H)-pyridone moieties as th