444772-01-4Relevant articles and documents
Metal-free intramolecular aziridination of allylic carbamates mediated by hypervalent iodine compounds
Deng, Qing-Hai,Wang, Jing-Cui,Xu, Zhen-Jiang,Zhou, Cong-Ying,Che, Chi-Ming
experimental part, p. 2959 - 2967 (2011/10/19)
An efficient and practical hypervalent iodine compound mediated metal-free intramolecular aziridination reaction of allylic carbamates was developed. Analytically pure aziridines were obtained in high yields by simple filtration of the reaction mixture. I
Rhodium(II)-catalyzed aziridination of allyl-substituted sulfonamides and carbamates
Padwa, Albert,Flick, Andrew C.,Leverett, Carolyn A.,Stengel, Thomas
, p. 6377 - 6386 (2007/10/03)
Several unsaturated sulfonamides underwent intramolecular aziridination when treated with PhI-(OAc)2, MgO, and catalytic Rh 2(OAc)4 to give bicyclic aziridines in excellent yield. Treatment of the resulting azabicyclic sul
Stereochemical aspects of the iodine(III)-mediated aziridination reaction of some cyclic allylic carbamates.
Padwa, Albert,Stengel, Thomas
, p. 2137 - 2139 (2007/10/03)
[reaction: see text] The iodine(III)-mediated aziridination reaction of an indolyl-substituted carbamate requires a Rh(II) catalyst and proceeds by a metallonitrene intermediate. Stepwise addition across the indole pi-bond followed by Rh(II) detachment ge