444772-06-9Relevant articles and documents
Rhodium(II)-catalyzed aziridination of allyl-substituted sulfonamides and carbamates
Padwa, Albert,Flick, Andrew C.,Leverett, Carolyn A.,Stengel, Thomas
, p. 6377 - 6386 (2007/10/03)
Several unsaturated sulfonamides underwent intramolecular aziridination when treated with PhI-(OAc)2, MgO, and catalytic Rh 2(OAc)4 to give bicyclic aziridines in excellent yield. Treatment of the resulting azabicyclic sul
Stereochemical aspects of the iodine(III)-mediated aziridination reaction of some cyclic allylic carbamates.
Padwa, Albert,Stengel, Thomas
, p. 2137 - 2139 (2007/10/03)
[reaction: see text] The iodine(III)-mediated aziridination reaction of an indolyl-substituted carbamate requires a Rh(II) catalyst and proceeds by a metallonitrene intermediate. Stepwise addition across the indole pi-bond followed by Rh(II) detachment ge