444904-74-9Relevant academic research and scientific papers
β-Fragmentation of primary alkoxyl radicals versus hydrogen abstraction: Synthesis of polyols and α,ω-differently substituted cyclic ethers from carbohydrates
Boto, Alicia,Hernandez, Dacil,Hernandez, Rosendo,Suarez, Ernesto
, p. 5310 - 5319 (2007/10/03)
The β-fragmentation of primary alkoxyl radicals, described in many cases as low-yielding and plagued by side reactions, can proceed in satisfactory yields using carbohydrate substrates. The only reaction that can compete significantly with the β-scission
Synthesis of α,ω-differently substituted cyclic ethers from carbohydrates by β-fragmentation of alkoxyl radicals
Boto, Alicia,Hernández, Rosendo,Suárez, Ernesto
, p. 1821 - 1824 (2007/10/03)
The β-fragmentation of alkoxyl radicals derived from easily available carbohydrates is a mild and efficient procedure to obtain unsymmetrical α,ω-disubstituted cyclic ethers.
