445027-76-9Relevant academic research and scientific papers
New insights into the reaction of t-butylhydroperoxide with dichloro- and dimethyl(dioxo)molybdenum(VI)
Groarke, Michelle,Gon?alves, Isabel S.,Herrmann, Wolfgang A.,Kühn, Fritz E.
, p. 108 - 112 (2002)
Lewis-base adducts of dichlorodioxomolybdenum(VI) and dimethyldioxomolybdenum(VI) react in an equilibrium reaction with excess t-butylhydroperoxide (TBHP) under the formation of a seven-coordinated molybdenum(VI) complexes displaying a η1-alkyl
Self-assembled bilayers as an anchoring strategy: Catalysts, chromophores, and chromophore-catalyst assemblies
Wang, Lei,Polyansky, Dmitry E.,Concepcion, Javier J.
supporting information, p. 8020 - 8027 (2019/06/13)
Anchoring strategies for immobilization of molecular catalysts, chromophores, and chromophorecatalyst assemblies on electrode surfaces play an important role in solar energy conversion devices such as dyesensitized solar cells and dye-sensitized photoelectrosynthesis cells. They are also important in interfacial studies with surface-bound molecules including electron-transfer dynamics and mechanistic studies related to small molecule activation catalysis. Significant progress has been made in this area, but many challenges remain in terms of stability, synthetic complexity, and versatility. We report here a new anchoring strategy based on selfassembled bilayers. This strategy takes advantage of noncovalent interactions between long alkyl chains chemically bound to a metal-oxide electrode surface and long alkyl chains on the molecule being anchored. The new methodology is applicable to the heterogenization of both catalysts and chromophores as well as to the in situ "synthesis" of chromophore-catalyst assemblies on the electrode surface.
Amphiphilic polypyridyl ruthenium complexes: Synthesis, characterization and aggregation studies
Bhand, Sujit,Lande, Dipali N.,Pereira, Eulália,Gejji, Shridhar P.,Weyhermüller, Thomas,Chakravarty, Debamitra,Puranik, Vedavati G.,Salunke-Gawali, Sunita
, p. 96 - 107 (2019/03/13)
Synthesis and characterization of five amphiphilic ruthenium(II) complexes of the type [Ru(Cn)3].(PF6)2 (Cn = 4,4′-dialkyl-2,2′-bipyridine, n = 5(4,4′-dipentyl), 6(4,4′-dihexyl), 7(4,4′-diheptyl), 8(4,4′-dioctyl), 9(4,4′-dinonyl)) have been investigated. Single crystal X-ray structures of 4,4′-dipentyl-2,2′-bipyridine (C5), 4,4′-dioctyl-2,2′-bipyridine (C8) ligands and [Ru(C5)3](PF6)2 complex are elucidated. Structural inferences are corroborated through the density functional theory. Molecular aggregations in these systems in aqueous and non-aqueous media have further been analyzed from FESEM experiments.
