4451-97-2Relevant academic research and scientific papers
Substitution effects on the formation of T-shaped palladium carbene and thioketone complexes from Li/Cl carbenoids
Molitor, Sebastian,Feichtner, Kai-Stephan,Kupper, Claudia,Gessner, Viktoria H.
, p. 10752 - 10762 (2014)
The preparation of palladium thioketone and T-shaped carbene complexes by treatment of thiophosphoryl substituted Li/Cl carbenoids with a Pd0 precursor is reported. Depending on the steric demand, the anion-stabilizing ability of the silyl moie
Rhodium (thiophosphinoyl)(trimethylsilyl)methanide and bis(thiophosphinoyl) methanide complexes: S～S vs. C～S coordination
Heuclin, Hadrien,Carenco, Sophie,Le Goff, Xavier-Frederic,Mezailles, Nicolas
experimental part, p. 1453 - 1461 (2012/06/05)
A comparative study of the coordination modes of a (thiophosphinoyl) (trimethylsilyl)methanide (1-·Li+) and bis(thiophosphinoyl)methanide (2-·Li+) ligand with RhI was carried out. Several complexes we
Formation of a palladium thioketone complex from a thiophosphinoyl stabilized Li/Cl carbenoid
Gessner, Viktoria H.
scheme or table, p. 4228 - 4231 (2011/10/03)
An in situ generated thiophosphinoyl stabilized Li/Cl carbenoid reacts with Pd(PPh3)4 with formation of a palladium thioketone complex. The presence of both the thiophosphinoyl and silyl groups as anion-stabilizing substituents is insufficient to stabilize the expected alkylidene complex and instead results in a rearrangement to the thioketone compound.
