445249-07-0

Basic information

• Product Name: 1-((E)-Hepta-4,6-dienyl)-2-methoxy-cyclohex-2-enol
• CAS NO: 445249-07-0
• Molecular Weight: 222.327
• Mol File: 445249-07-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-((E)-Hepta-4,6-dienyl)-2-methoxy-cyclohex-2-enol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((E)-Hepta-4,6-dienyl)-2-methoxy-cyclohex-2-enol(445249-07-0)
• EPA Substance Registry System: 1-((E)-Hepta-4,6-dienyl)-2-methoxy-cyclohex-2-enol(445249-07-0)

Safety Data

• Hazardous Substances Data: 445249-07-0(Hazardous Substances Data)

Upstream product

• 23740-37-6 2-methoxycyclohex-2-en-1-one 
• 93606-07-6 (E)-4,6-heptadienylmagnesium bromide 
• 10316-66-2 2-hydroxy-2-cyclohexen-1-one 
• 38461-13-1 2,2-dimethoxycyclohexanone 

Relevant articles and documents

Intramolecular 4+3 cycloadditions. A cyclohexenyl cation, its halogenated congener and a quasi-Favorskii rearrangement

Treatment of alkoxycyclohexenols bearing a tethered diene substituent with a Lewis acid results in intramolecular 4+3 cycloaddition with complete endo selectivity. A cycloadduct bearing a bromo substituent at a bridgehead position undergoes a quasi-Favorskii rearrangement in near quantitative yield upon reaction with lithium aluminum hydride.