445411-74-5Relevant academic research and scientific papers
Asymmetric induction in the neber rearrangement of simple ketoxime sulfonates under phase-transfer conditions: Experimental evidence for the participation of an anionic pathway
Ooi, Takashi,Takahashi, Makoto,Doda, Kanae,Maruoka, Keiji
, p. 7640 - 7641 (2002)
Phase-transfer catalysis has been successfully utilized for the Neber rearrangement of simple ketoxime sulfonates. For instance, treatment of (Z)-1a with p-toluenesulfonyl chloride (1.2 equiv), tetrabutylammonium bromide (5 mol %) and MeOH (10 equiv) in t
