446867-33-0Relevant academic research and scientific papers
2,2-Disubstituted analogues of the natural hormone 1α,25-dihydroxyvitamin D3: Chemistry and biology
Posner, Gary H.,Woodard, Benjamin T.,Crawford, Kenneth R.,Peleg, Sara,Brown, Alex J.,Dolan, Patrick,Kensler, Thomas W.
, p. 2353 - 2365 (2007/10/03)
Six new 2,2-disubstituted analogues of the natural hormone calcitriol have been prepared. Chemical novelty includes (1) the first example of an inverse-electron-demand Diels-Alder cycloaddition using a pyrone diene and a difluorinated vinyl ether dienophi
