448896-88-6Relevant articles and documents
Chiron approach strategy to the bicyclic oxazolidinylpiperidine: A building block for preparing mono-and bi-cyclic iminosugars
Kalamkar, Navnath B.,Dhavale, Dilip D.
, p. 6363 - 6365 (2012/01/02)
A chiron approach to the synthesis of bicyclic oxazolidinylpiperidine, a synthetically potential building block for preparing mono-and bi-cyclic iminosugars, is reported from D-glucose using ring closing metathesis as the key step.
General approach to glycosidase inhibitors. Enantioselective synthesis of deoxymannojirimycin and swainsonine
Martin, Ruben,Murruzzu, Caterina,Pericas, Miquel A.,Riera, Antoni
, p. 2325 - 2328 (2007/10/03)
(Chemical Equation Presented) Deoxymannojirimycin (2) and swainsonine (4) have been synthesized from each enantiomer of the same bicyclic carbarnate precursor 7. The key intermediate was prepared by a simple and efficient three-step synthesis involving RCM of the diene 8, which in turn is easily accessible in any configuration from enantiomerically enriched 2,3-epoxy-4-penten-1-ol 9.