449207-23-2Relevant academic research and scientific papers
Synthesis and reactivity of novel cyclometallated complexes derived from [C,N,O] terdentate ligands. Crystal structure of [Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)C6H 4]}(PPh3)]
Fernandez, Alberto,Vazquez-Garcia, Digna,Fernandez, Jesus J.,Lopez-Torres, Margarita,Suarez, Antonio,Castro-Juiz, Samuel,Vila, Jose M.
, p. 398 - 404 (2002)
Treatment of the Schiff base ligands 2,3,4-(MeO)3C6H2C(H)=N[2-(OH)C6H 4], a, and 2,3,4-(MeO)3C6H2-C(H)=N[2-(OH)-4-MeC 6H4], b, with palladium(II) acetate in toluene gave the cyclometallated complexes [Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)C6H 4]}]n, 1a, and [Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)-4-MeC6H 4]}]n, 1b, respectively, as air stable solids, with the [C,N,O] ligand terdentate after deprotonation of the -OH group. Reaction of the cyclometallated complexes with triphenylphosphine gave the mononuclear species [Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)C6H 4]}(PPh3)], 2a, and [Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)-4-MeC6H 4]}-(PPh3)], 2b, with cleavage of the polynuclear structure. The molecular structure of 2a has been determined by X-ray crystallography. Treatment of 1a and 1b with the diphosphines dppm, dppp, dppb, dpppe and dppf in a 1:2 molar ratio afforded the dinuclear cyclometallated complexes [(Pd{2,3,4-(MeO)3C6HC (H)=N[2-(O)C6H4]})2{μ-PPh2 (CH2)nPPh2}] (3a: n = 1; 4a: n = 3; 5a: n = 4; 6a: n = 5), [(Pd{2,3,4-(MeO)3 C6HC(H)=N[2-(O)C6H4]})2(μ-PPh 2C5H4FeC5H4PPh 2)], 7a, [(Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)-4-MeC6H 4]})2{μ-PPh2(CH2) nPPh2}] (3b: n = 3; 4b: n = 4) and [(Pd{2,3,4-(MeO)3C6HC(H)=N[2-(O)-4-MeC6H 4]})2(μ-PPh2C5H4 FeC5H4PPh2)], 5b, as air stable solids. Treatment of 1a and 1b with an excess of mono- or diphosphine did not produce cleavage of the Pd-Ochelating bond.
