449740-09-4Relevant academic research and scientific papers
Synthesis, photophysics, electrochemistry and binding studies of zinc(II) dithiolate crown complexes
Yam, Vivian Wing-Wah,Pui, Yung-Lin,Cheung, Kung-Kai,Zhu, Nianyong
, p. 536 - 542 (2002)
A series of zinc(II) dithiolate complexes containing ligands with benzo-15-crown-5 (dic), benzo-18-crown-6 (dic-18-6), 10-thiabenzo-15-crown-5 (dic-S), 10-selenabenzo-15-crown-5 (dic-Se) and 7,10,13-trithiabenzo-15-crown-5 (dic-3S) moieties have been synthesized and characterized, and their photophysics and electrochemistry studied. The metal ion-binding properties have been investigated by electronic absorption, emission and 1H NMR spectroscopy. The X-ray crystal structure of [Zn(SC6H4-CH3-p)2(dic-3S)] (5) has also been determined.
