449764-33-4Relevant academic research and scientific papers
C-P bond formation of cyclophanyl-, and aryl halides: Via a UV-induced photo Arbuzov reaction: A versatile portal to phosphonate-grafted scaffolds
Br?se, Stefan,Hassan, Zahid,Nieger, Martin,O?wald, Simon,Zippel, Christoph
, p. 3309 - 3312 (2022/02/11)
A new versatile method for the C-P bond formation of (hetero)aryl halides with trimethyl phosphite via a UV-induced photo-Arbuzov reaction, accessing diverse phosphonate-grafted arenes, heteroarenes and co-facially stacked cyclophanes under mild reaction
(Benzene-1,3,5-triyl)tris[phosphine] (C6H3(PH2)3) and (benzene-1,3,5-triyl)tris[phosphonic acid] (C6H3[P(O)(OH)2]3). Absence of hydrogen bonding in solid primary phosp
Reiter, Stephan A.,Assmann, Bernd,Nogai, Stefan D.,Mitzel, Norbert W.,Schmidbaur, Hubert
, p. 1140 - 1150 (2007/10/03)
The prolonged photo-Arbuzov reaction (3 weeks, Hg lamp) of 1,3,5-trichloro-benzene with a large excess of trimethyl phosphite (as a solvent) at 50° gives moderate yields of dimethyl (3,5-dichlorophenyl)phosphonate (1; 14.5%), tetramethyl (5-chloro-1,3-phe
