4508-50-3Relevant academic research and scientific papers
Carbon-carbon cleavage of aryl diamines and quinone formation using sodium periodate: a novel application
Telvekar, Vikas N.,Takale, Balaram S.
, p. 3940 - 3943 (2010)
A first novel synthetic utility of sodium periodate for aryl diamine carbon-carbon cleavage is described. Aryl 1,2-diamine compounds were successfully converted into corresponding nitriles, while the developed method is also useful for the preparation of quinones from corresponding aryl 1,4-diamine compounds. The advantages of this protocol are shorter reaction time and mild reaction conditions to obtain moderate to good yields.
CUCN-MEDIATED ONE POT PRODUCTION OF CINNAMONITRILE DERIVATIVES
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Paragraph 0043; 0046 - 0048; 0057, (2015/02/19)
The present invention discloses a cheaper and practical protocol for the construction of a wide variety of o-cyanocin-namonitrile and their structural analogues that proceeds with good yields in a single step using CuCN as the only reagent.
