451491-95-5Relevant academic research and scientific papers
Synthesis of unsaturated β-amino acid derivatives from carbamates of the Baylis-Hillman products
Ciclosi, Marco,Fava, Cristiana,Galeazzi, Roberta,Orena, Mario,Sepulveda-Arques, José
, p. 2199 - 2202 (2007/10/03)
By treatment with a catalytic amount of DBU in DCM, N-p-toluenesulphonyl carbamates 6a-c, prepared starting from the corresponding Baylis-Hillman adducts, gave (E)-2-(p-toluenesulphonylaminomethyl)propenoates 3a-c, exclusively. On the contrary, changing D
Synthesis of quinolines from the Baylis-Hillman acetates via the oxidative cyclization of sulfonamidyl radical as the key step
Kim, Jae Nyoung,Chung, Yun Mi,Im, Yang Jin
, p. 6209 - 6211 (2007/10/03)
Ethyl 3-quinolinecarboxylates 5 were synthesized in good to moderate yields from the Baylis-Hillman acetates 1 via the oxidative cyclization reaction of the N-tosylamidyl radical, which was generated from the rearranged tosylamide derivatives 2 by iodoben
