452093-85-5

Basic information

• Product Name: C₆H₅CHCSn(C₄H₉)3C₆H₄(p-NO₂)
• Synonyms: C₆H₅CHCSn(C₄H₉)3C₆H₄(p-NO₂)
• CAS NO: 452093-85-5
• Molecular Weight: 514.295
• Mol File: 452093-85-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₅CHCSn(C₄H₉)3C₆H₄(p-NO₂)(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₅CHCSn(C₄H₉)3C₆H₄(p-NO₂)(452093-85-5)
• EPA Substance Registry System: C₆H₅CHCSn(C₄H₉)3C₆H₄(p-NO₂)(452093-85-5)

Safety Data

• Hazardous Substances Data: 452093-85-5(Hazardous Substances Data)

Upstream product

• 1942-30-9 4-(phenylethynyl)nitrobenzene 
• 688-73-3 tri-n-butyl-tin hydride 

Relevant articles and documents

Ortho substituents direct regioselective addition of tributyltin hydride to unsymmetrical diaryl (or heteroaryl) alkynes: An efficient route to stannylated stilbene derivatives

An unprecedented ortho-directing effect (ODE) in diaryl alkynes 1 (R=electron-withdrawing or electron-donating group) promotes regioselective addition of tributyltin hydride to the triple bond and afforded efficiently stannylated unsymmetrical 1,2-diaryl olefins 2. The precise contributions of steric, electronic, and coordinative factors, which control this regioselectivity are highlighted. The results are rationalized in terms of electronic polarization across the alkyne bond, induced by the ortho substituent whatever its electronic nature.