453525-05-8

Basic information

• Product Name: methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside
• Synonyms: methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside
• CAS NO: 453525-05-8
• Molecular Weight: 1101.15
• Mol File: 453525-05-8.mol

Chemical Properties

• CAS DataBase Reference: methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside(453525-05-8)
• EPA Substance Registry System: methyl 6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-2,3,4-tri-O-benzoyl-α-D-glucopyranoside(453525-05-8)

Safety Data

• Hazardous Substances Data: 453525-05-8(Hazardous Substances Data)

Upstream product

• 137886-82-9 2,3,4,6-tetra-O-acetyl-5-thio-D-glucopyranose 
• 453525-17-2 2,3,4,6-tetra-O-benzoyl-5-deoxy-5-thio-α-D-glucopyranose 
• 453525-11-6 tetrahydropyran-2-yl 2,3,4,6-tetra-O-acetyl-5-deoxy-5-thio-α-D-glucopyranoside 
• 453524-96-4 tetrahydropyran-2-yl 5-deoxy-5-thio-α-D-glucopyranoside 
• 137886-82-9 2,3,4,6-Tetra-O-acetyl-5-thio-α-D-glucopyranose 
• 34234-44-1 methyl 2,3,4-tri-O-benzoylglucopyranoside 
• 453524-99-7 2,3,4,6-tetra-O-benzoyl-5-deoxy-5-thio-α-D-glucopyranosyl trichloroacetimidate 

Relevant articles and documents

Synthetic studies on oligosaccharides composed of 5-thioglucopyranose units

Glycosylation reactions of 5-thioglucopyranosyl trichloroacetimidates bearing ethereal protective groups at the 2-O-position 14-15, and 37 proceed smoothly to give α-glycosides stereoselectively by using a catalytic amount of silyl triflate. This methodol

β-selective glycosylation of 5-thioglucopyranose derivatives; syntheses of β-(1 → 6) linked 5′-thioglucopyranosyl disaccharides

β-Stereoselctive and effective glycosylation with 5-thioglucopyranose was achieved by performing the reaction with pivaloyl- or benzoyl-protected glucopyranosyl trichloroacetimidates and BF3OEt2, a glycosyl activator, when C6-OH gluc